MONOETHANOLAMIDE BASED NON-IONIC GEMINI SURFACTANTS FROM RENEWABLE SOURCES: SYNTHESIS, CHARACTERIZATION AND ANTICORROSION STUDY
Keywords:
Gemini Surfactant, Spectroscopy Characterization, SEM, Anticorrosion StudyAbstract
The synthesis of novel non-ionic Gemini surfactants were carried out in two stages in the present research work. Initially ethanol amine was converted into fatty amides by using four different fatty acid namely lauric, myristic, palmitic and oleic acid followed by reaction with 1,2,7,8-diepoxyoctane to form targeted non-ionic Gemini surfactants. The structure of new synthesized Gemini surfactants were confirmed by using FTIR, 1H-NMR and 13C-NMR spectroscopy. Corrosion inhibition efficiency was determined by weight loss method for different concentration. The shapes of synthesized surfactants were determined by Scanning electron microscopy. SEM study of these surfactants revealed that particles are in spherical and distorted spherical in shape. The synthesized Gemini surfactants have good inhibition efficiency against carbon steel.
References
Broze G. Handbook of surfactant, Surfactant science series, part A: Properties, 1st Ed., Marcel Dekker Inc: New York. 82; 1999:76-78.
Brita MF, Krister H, Eva GK, Karin B. Fatty amide ethoxylates: synthesis and self assembly. Journal of Surfactant and Detergent.c4(2); 2001: 175-183.
Hait SK, Moulik SP. Gemini surfactants: a distinct class of self-assembling molecules. Current Science. 82(9); 2012:1101-1111.
Janardhan R, Vijayabaskar V, Reddy BSR. Synthesis and characterisation of sulfonated dimeric malenised soya fatty acid : A novel Gemini surfactant. J. Surface Sci. Technol. 28(3-4); 2012:163-178.
Gawali IT, Usmani GA. Synthesis, characterization and some properties of glycerol ester based non-ionic gemini surfactant with 1, 2, 7, 8 -diepoxideoctane as spacer. International journal of science and research.3(10): 2014:580-584.
Wenjian Z., Liguo Z., Zhaoyun D. Synthesis and performance of nonionic Gemini surfactant di-glycerol 2, 9-dihexyldecanedioate. Journal of Dispersion Science and Technology. 30 (9); 2009:1161-1166.
Adewale A, Andrea G, Thomas W. Properties of sodium phosphate hydroxy ethanolamide gemini surfactant synthesized from the seed oil of Luffa cylindrical. Central Europian Journal of Chemistry. 11(8); 2013:368-1380.
Aratani K, Oida T, Shimizu T, Hayashu Y. Preparation and properties of Gemini surfactant from tartaric acid. Communications presented as a las Jornadas del Comite Espanol de la Detergencia. 28; 1998: 45-46.
Anno W, Engberts JBFN. Synthesis of nonionic reduced-sugar bola amphiphiles and surfactants with an α,ω-diamin-(oxa) alkyl spacer. Science Direct Tetrahedron. 63; 2007:10622-10629.
Gawali IT, Usmani GA. Study of physico-chemical properties of glycerol ester based non-ionic gemini Surfactant. International Journal of Science and Research. 3(11); 2014:580-584
Kandeel EM. Synthesis and performance of glycerol ester-based non-ionic surfactants. Der Chemica Sinica. 2 (3); 2011: 88-98.
Thomas MS. Analysis of surfactant, second edition, BASF Corporation New York, Vol. 96. Detergent. 2001: 175-183.
Furniss BS, Hannaford AJ, Smith PWG, Tatchell AR. Vogel’s text book of practical organic chemistry, Addision Wesley Longman, Inc, 1989:1413-1434.
Harwood LM, Moody C J, Percy JM “Experimental Organic Chemistry, Standard and Microscale, second edition, Wiley Pvt. Ltd , India, 2011.
Patial P, Shaheen A, Ahmad I. Synthesis, characterization and evaluation of the surface active properties of novel cationic imidazolium gemini surfactant. Journal of Surfactant & Detergent. 17(2); 2013: 253-260.
Branzoi V, Branzoi F, Baibarac, M. The inhibition of the corrosion of Armco iron in HCl solutions in the presence of surfactants of the type of N-alkyl quaternary ammonium salts. Mater. Chem. Phys. 65 (3); 2010: 288-297.
Xinkuai H, Yumei J, Chen L, Luye W. Inhibition properties and adsorption behaviour of imidazole and 2-phenyl-2-imidazoline on aa5052 in 1.0 m hcl solution. Corrosion Science. 83; 2014:124-136.
Atkin R, Craig, VSJ, Wanless EJ, Biggs S. The influence of chain length and electrolyte on the adsorption kinetics of cationic surfactants at the silica-aqueous solution interface. Journal of Colloid and Interface Science. 266(2):2003, 236-244.
Tang LB, Mu GN, Liu GH. The effect of neutral red on the corrosion inhibition of cold rolled steel in 1.0 m hydrochloric acid. Corrosion Science. Corros. Sci. 45; 2003: 2251-2262.
Manjula P, Manonmani S, Jayaram P, Rajendran S. Corrosion behaviour of carbon steel in the presence of N-cetyl-N,N,Ntrimethylammoniumbromide, Zn and calcium gluconate. 48; 2001: 319-324.
Additional Files
Published
How to Cite
Issue
Section
License
Copyright (c) 2018 International Educational Journal of Science and Engineering
This work is licensed under a Creative Commons Attribution 4.0 International License.
